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Document Details
Document Type
:
Article In Journal
Document Title
:
A Novel Poly(p-phenylene) Containing Alternating Poly(perfluorooctylethyl acrylate-co-methyl methacrylate) and Polystyrene Grafts by Combination of Atom Transfer Radical Polymerization and Suzuki Coupling Processes
A Novel Poly(p-phenylene) Containing Alternating Poly(perfluorooctylethyl acrylate-co-methyl methacrylate) and Polystyrene Grafts by Combination of Atom Transfer Radical Polymerization and Suzuki Coupling Processes
Document Language
:
English
Abstract
:
A poly(p-phenylene) (PP), carrying perfectly alternating, well-defined poly(perfluorooctylethyl acrylate-co-methyl methacrylate) [P(FEA-co-MMA)] and polystyrene (PS) side chain grafts, was synthesized by the combination of atom transfer radical polymerization (ATRP) and Suzuki cross-coupling processes. First, dibromobenzene and diboronic ester functional macromonomers of P(FEA-co-MMA) and PS, respectively, were prepared by ATRP. In the second step, PP with lateral alternating P(FEA-co-MMA) and PS chains was synthesized by a Suzuki coupling reaction in the presence of Pd(PPh3)(4) catalyst. The wetting behavior of the polymers was studied by measurements of the static contact angle theta of thin films (200-400 nm thickness) using water and n-hexadecane as wetting liquids. The obtained fluorinated PP showed high static contact angles with both interrogating liquids, exhibiting simultaneously hydrophobic (theta(w) = 111 degrees) and lipophobic (theta(h) = 67 degrees) properties.
ISSN
:
0887-624X
Journal Name
:
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume
:
50
Issue Number
:
23
Publishing Year
:
1433 AH
2012 AD
Article Type
:
Article
Added Date
:
Tuesday, July 11, 2017
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
y Durmaz
Durmaz, y
Researcher
e Sahkulubey
Sahkulubey, e
Researcher
y Yagci
Yagci, y
Researcher
E Martinelli
Martinelli, E
Researcher
G Galli
Galli, G
Researcher
Files
File Name
Type
Description
42066.pdf
pdf
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