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Document Type |
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Article In Journal |
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Document Title |
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Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide |
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Subject |
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Chemistry |
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Document Language |
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English |
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Abstract |
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The asymmetric unit of the title compound, C6H 16N+·C3H2N3S 3-, contains two independent ion pairs. The 2,4,6-trithioxo-1,3,5-triazinan-1-ide anion features an almost planar sixmembered ring (r.m.s. deviations = 0.009 and 0.018 Å) having exocyclic doublebond S atoms. The anions interact by N - H⋯S hydrogen bonds to generate a chain running along [110]. The triethylammonium cations are hydrogen bonded to the anions with the ammonium H atom forming a hydrogen bond to the negativelycharged N atom of the anion. In the crystal structure, both triethylammonium cations are disordered over two orientations with equal occupancies. |
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ISSN |
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1600-5368 |
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Journal Name |
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Acta Crystallographica Section E: Structure Reports Online |
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Volume |
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67 |
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Issue Number |
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9 |
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Publishing Year |
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1432 AH
2011 AD |
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Article Type |
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Article |
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Added Date |
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Saturday, December 10, 2011 |
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Researchers
| H -P Li | Li, H -P | Researcher | Doctorate | |
| Seik Weng Ng | Ng, Seik Weng | Researcher | Doctorate | seikweng@um.edu.my |
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